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Preliminary Studies about Synthesis and Electrical Properties of Ruthenium Doped Lanthanum Strontium Titanate as a Potential Anode of Solid Oxide Fuel Cells

机译:钌掺杂钛酸镧锶锶作为固体氧化物燃料电池阳极的初步研究

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The lanthanum strontium titanate (LST) is one of the most representative alternative anode materials. Although it shows low catalytic properties, the disadvantage could be improved by doping of ruthenium which is widely used as catalyst under steam reforming reaction or oxidation reaction. The ruthenium doped lanthanum strontium titanates (LSTRs) powders were synthesized by complex EDTA-citrate method showing well crystallinity. Additionally, the prepared samples were evaluated through various experimental tests. For example, the stability in the reducing atmosphere and chemical compatibility with YSZ electrolyte such as reactivity test in high temperature were confirmed by XRD (X-ray diffraction). And electrical conductivity in wet H_2 atmosphere at 900 °C is about 350.6 S/cm, 342.4 S/cm and 179.1 S/cm with sintered bar of LST, LSTR0.02 and LSTR0.05, respectively.
机译:钛酸镧锶(LST)是最具代表性的替代阳极材料之一。尽管它显示出低的催化性能,但是可以通过掺杂钌来改善该缺点,钌在蒸汽重整反应或氧化反应中被广泛用作催化剂。采用络合EDTA-柠檬酸盐法合成了钌掺杂的钛酸镧锶锶(LSTRs)粉末,具有良好的结晶性。另外,通过各种实验测试对制备的样品进行评估。例如,通过XRD(X射线衍射)确认了在还原气氛中的稳定性和与YSZ电解质的化学相容性,例如高温下的反应性试验。在900°C的湿H_2气氛中,使用LST,LSTR0.02和LSTR0.05的烧结棒,电导率分别约为350.6 S / cm,342.4 S / cm和179.1 S / cm。

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