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New approach to estimate furan contents in transformer oil using spectroscopic analysis

机译:利用光谱分析估算变压器油中呋喃含量的新方法

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The presence of furan derivatives in aged-transformer oil has been one of the key indicators for solid dielectric deterioration. Identification and quantification of furan derivatives are currently performed using high performance liquid chromatography (HPLC) or gas chromatography-mass spectrometry (GC/MS) based on ASTM D5837 standard. Although these techniques are well developed, they call for an expert personal to conduct the test and to analyse its results. Moreover, the test is relatively expensive and the analysis of oil sample may take days as most utilities sending transformer oil samples to external laboratories to be tested. This paper introduces a novel approach to determine the furan concentration within power transformer dielectric oil through ultraviolet to visible (UV-Vis) spectroscopic analysis for oil samples. Furan concentration in transformer oil would determine the absorption intensity in UV-Vis spectral range and hence the correlation between furan concentration and spectral response of transformer oil can be identified. Experimental results show that the new technique is reliable, economic and easy to be implemented on site to identify the furan concentration level in transformer oil instantly.
机译:老化的变压器油中呋喃衍生物的存在一直是固体介电质劣化的关键指标之一。呋喃衍生物的鉴定和定量目前使用基于ASTM D5837标准的高效液相色谱(HPLC)或气相色谱-质谱(GC / MS)进行。尽管这些技术已经很好地开发了,但它们需要专家来进行测试并分析其结果。而且,该测试是相对昂贵的,并且由于大多数公用事业公司将变压器油样品发送到要测试的外部实验室,因此油样的分析可能需要几天的时间。本文介绍了一种新颖的方法,可通过油样品的紫外到可见(UV-Vis)光谱分析来确定电力变压器介电油中的呋喃浓度。变压器油中的呋喃浓度将决定UV-Vis光谱范围内的吸收强度,因此可以确定呋喃浓度与变压器油的光谱响应之间的相关性。实验结果表明,该新技术可靠,经济,易于现场实施,可快速识别变压器油中的呋喃浓度。

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