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Removal of Phenol from Water by Adsorption onto Sewage Sludge Based Adsorbent

机译:通过吸附在污水污泥的吸附剂中除去苯酚从水中除去苯酚

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The aim of this study is to evaluate the adsorption performances of sewage sludge based adsorbent SSBA for the removal of phenol from water. The SSBA was prepared by chemical activation with H_2SO_4 in a mass ratio of 1:1, followed by a pyrolysis at 650°C for 1 h under inert atmosphere. Phenol removal by SSBA was investigated using kinetic and equilibrium experiments. The results demonstrate that phenol sorption to the SSBA reached equilibrium at 2 h with the maximum sorption capacity of 26.16 mg.g~(-1) under given experimental conditions (initial Phenol concentration range = 40-200 mg.l~(-1); adsorbent dose = 5.0 g.l~(-1) and temperature = 20°C). The phenol removal was high and relatively constant at (pH<pKa), whereas the phenol removal decreased sharply as the solution pH approached a highly alkaline condition (pH>pKa).The results indicate that the pseudo second order model was suitable for describing the kinetic data. Regarding the equilibrium data, the Freundlich isotherm was fitted well. This study demonstrates that SSBA could be used for phenol removal from water.
机译:本研究的目的是评估基于污泥吸附剂SSBA的吸附性能用于从水中去除苯酚。 1在650,随后热解℃,惰性气氛下1个小时:在SSBA通过以1:1的质量比H_2SO_4化学活化制备。利用动力学和平衡实验脱酚由SSBA进行了研究。结果表明,苯酚吸附到SSBA在2小时达到平衡与26.16的最大吸附能力mg.g〜(-1)给定的实验条件(下初始苯酚浓度范围= 40-200 mg.l〜(-1) ;吸附剂剂量= 5.0〜GL(-1)和温度= 20℃)。苯酚去除率高,并在(pH为相对恒定的Ka值),而作为溶液的pH值接近高碱性条件下(pH脱酚急剧下降> pKa值)。结果表明,该伪二阶模型是适用于描述的动力学数据。关于平衡数据时,Freundlich等温装配好。这项研究表明,SSBA可用于从水中脱酚。

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