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TAR/CH_4 REFORMING BY CATALYTIC BED MATERIALS IN A BIOMASS FLUIDISED BED GASIFIER

机译:焦油/ CH_4催化床材料在生物质流化床气化器中的重整

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A study on in-bed catalytic material reforming of tar/methane (CH_4) has been performed in the 150 kW allothermal biomass gasifier at Mid Sweden University (MIUN). The MIUN gasifier, built for research on synthetic fuel production, is a dual fluidised bed gasifier (DFBG). The syngas for automotive fuels synthesis has a strict specification of impurities. The biggest challenge for biomass fluidised-bed gasification is the reforming of tars and CH_4. Internal reforming should be considered before downstream reforming. The MIUN gasifier has a unique design suitable for in-bed tar/CH_4 catalytic reforming and continuously internal regeneration of the reactive bed material. The experimental tests are carried out in three cases: 1) basic condition with silica sand (no catalytic activity), 2) calcinated olivine, and 3) Fe-impregnated olivine (10%wtFe/Olivine Catalyst). The measurement results have been evaluated by comparing tar/CH_4 content in the syngas from the gasifier operated under different operation conditions. These results in BFB mode have initiated the ongoing investigations of the catalytic effects and regeneration in DFB mode. It can be concluded that the Fe-impregnated olivine showed a surprising low reactivity for tar and CH_4 reforming in the BFB model
机译:在瑞典大学(MIUN)的150 kW艾温生物量气化器中,在150 kW含有焦油/甲烷(CH_4)的床上催化材料重整研究。 MIU气化器为合成燃料生产研究,是双流体化床气化器(DFBG)。用于汽车燃料合成的合成气具有严格的杂质规范。生物质流化床气化的最大挑战是焦油和CH_4的重整。在下游改革之前应考虑内部改革。 Miun气化炉具有独特的设计,适用于床上沥青/ CH_4催化重整和连续内部再生的反应床材料。实验试验在三种情况下进行:1)硅砂(无催化活性),2)煅烧橄榄石和3)Fe浸渍橄榄石(10%WTFE / OLIVINE催化剂)的基本条件。通过将Syngas中的焦油/ CH_4含量与在不同操作条件下操作的气化器中的焦油/ CH_4含量进行比较来评估测量结果。这些结果在BFB模式下开始了DFB模式下的催化作用和再生的持续研究。可以得出结论,Fe浸渍的橄榄石在BFB模型中表现出焦油和CH_4重整的令人惊讶的低反应性

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