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BIOMASS GASIFICATION IN BUBBLING FLUIDIZED BED: EFFECT OF BIOMASS TYPE ON SYNGAS PROPERTIES

机译:泡泡化流化床中的生物质气化:生物质型对合成气特性的影响

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The gasification characteristics of three different biomass feedstock samples (straw pellet, softwood pellet and torrefied wood chips) were investigated in this study. The effect of biomass type on gas composition, gas yield, lower heating value (LHV), carbon conversion efficiency, the amounts of tar and sulfur compounds were investigated in laboratory scale bubbling fluidized bed gasifier using air as a gasification agent and quartz as a bed material. Permanent gases were analyzed by gas chromatograph (GC) equipped with a flame ionization detector. The amounts of total sulfur and individual sulfur compounds (hydrogen sulfide, carbonyl sulfide and methyl mercaptane) were determined by UV fluorescence and GC PFPD (pulsed flame photometric detector) techniques, respectively. Conventional gravimetric (CEN/TS 15439) method was used for sampling and analysis of tar compounds. Torrefied wood chips produced much lower tar during gasification, in comparison to the softwood pellet sample. The syngas obtained from straw pellet had the highest calorific value, 4.40 MJ/Nm~3, while torrefied wood had the lowest calorific value, 3.50 MJ/Nm~3.
机译:在本研究中研究了三种不同生物量原料样品(草丸,软木颗粒和撕纸)的气化特性。上气体组成,气体产量生物量类型,较低的热值(LHV),碳转化效率的效果,焦油和硫化合物的量以实验室规模进行了调查使用空气作为气化剂和石英作为床鼓泡流化床气化炉材料。通过配备有火焰电离检测器的气相色谱仪(GC)分析永久气体。通过UV荧光和GC PFPD(脉冲火焰光度检测器)技术分别测定总硫和单个硫化合物(硫化氢,碳硫化物和甲基硫醇)的量。常规重量(CEN / TS 15439)方法用于抽样和分析焦油化合物。与软木颗粒样品相比,雾化木屑在气化过程中产生了很大的焦油。从稻草颗粒中获得的合成气量具有最高的热值,4.40 mJ / nm〜3,而烘焙木材具有最低的热值,3.50 mj / nm〜3。

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