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Effect of Admixture on Mechanical Behavior and Micro-Structure of Sulphoaluminate Composite Material

机译:掺合料对硫铝酸盐复合材料力学行为和微观结构的影响

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Mechanical behavior of sulphoaluminate cement (SAC) mortar mixed slag (SL),fly ash (FA) and combined admixture were studied in the study,at the same time,hydration products and micro-structure were analyzed with XRD and SEM for making clear hydration mechanism.Test results show that early period strength of SAC mortar decreased,and strength contribution rate of admixture is combined admixture (slag + fly ash) > slag > fly ash on the same content due to the combined admixture is more beneficial to accelerate hydration.Yet strength increase of SAC mortar mixed admixture after cured 60d is not obvious,which was not large different with pure SAC mortar.A large amount of ettringite and gel produced during 1d period of SAC paste,but with the hydration carrying on,diffraction peak of hydration products (ettringite and gel) and unhydrated calcium sulphoaluminate change little,which means hydration degree at 1d is higher.Diffraction peak of ettringite and gel at different curing period is lower when mixed admixture in matrix,the amount of ettringite and gel increased and unhydrated calcium sulphoaluminate decreased with hydration carrying on,which means early hydration speed slow down when introduction of admixture into SAC matrix.
机译:研究了硫铝酸盐水泥(SAC)砂浆混合渣(SL),粉煤灰(FA)和混合掺合料的力学性能,同时,用XRD和SEM分析了水合产物和微观结构,以使水合清晰试验结果表明,SAC砂浆的早期强度降低,掺合料的掺量(矿渣+粉煤灰)>矿渣>粉煤灰的掺量相同,由于掺合料的掺和量对促进水化作用更有利。固化60d后SAC砂浆掺合料的强度增加并不明显,与纯SAC砂浆差别不大。SAC糊剂1d期间产生大量钙矾石和凝胶,但随着水化的进行,衍射峰增大。水合产物(钙矾石和凝胶)和未水合硫铝酸钙变化不大,这意味着在1d时水合度较高。钙矾石和凝胶在不同固化时间的衍射峰较低当在基质中混合掺合料时,随着水合作用的进行,钙矾石和凝胶的量增加,未水合的硫代铝酸钙减少,这意味着当将掺合剂引入SAC基质时,早期水合速度减慢。

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