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Crystallization kinetics of poly(ethylene terephthalate)/ poly(ethylene 2,6-naphthalate)/DBS blends

机译:聚对苯二甲酸乙二醇酯/ 2,6-萘二甲酸乙二醇酯/ DBS共混物的结晶动力学

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The crystallization kinetics of poly(ethylene terephthalate)/poly(ethylene 2,6-naphthalate)/DBS blends were investigated by DSC. The results showed that a little nucleating agent could increase the crystallization rate obviously. When the content of DBS increase (more than 3%), the crystallization rate decrease gradually. The change of apparent activative energy of the blends was similar to n from Avrami equation. The nucleating affected nucleation rate and did not affected equilibrium melting points.
机译:通过DSC研究了聚对苯二甲酸乙二醇酯/ 2,6-萘二甲酸乙二醇酯/ DBS共混物的结晶动力学。结果表明,少量成核剂可以明显提高结晶速率。当DBS的含量增加(大于3%)时,结晶速率逐渐降低。共混物的表观活化能的变化与Avrami方程中的n相似。成核影响成核速率并且不影响平衡熔点。

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