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Photoluminescence Measurement of Poly (Ethylene Terephthalate) Films

机译:聚对苯二甲酸乙二酯薄膜的光致发光测量

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The poly(ethylene terephthalate)-PET is widely used in dielectric insulation, so the study on its luminescence characters is valuable. The Photolumi-nescence-PL intensity and spectra of PET films were detected by the home-made set-up. Experiment shows: The PL intensity with exponential decay along with the time. There are emitting peaks about 300-400nm, 500-600nm and nearby 700nm in the PL accumulative spectra, and the peak region nearby 700nm is a little higher. The absorption spectra were tested by TU-1901 double beam UV-Vis spectrophotometer. The calculation shows that energy gap of PET films is about 3.96eV according to the absorption edge of the spectra. The results we obtained from the PL measurement indicate that this method will contribute to understanding the trap distribution and luminescent micro-mechanism of Insulation Polymers.
机译:聚对苯二甲酸乙二醇酯-PET被广泛用于介电绝缘,因此对其发光特性的研究具有重要的价值。通过自制装置检测PET薄膜的光致发光-PL强度和光谱。实验表明:PL强度随时间呈指数衰减。 PL累积光谱中大约有300-400nm,500-600nm和700nm附近的发射峰,而700nm附近的峰区域要高一些。通过TU-1901双光束UV-Vis分光光度计测试吸收光谱。计算表明,根据光谱的吸收边缘,PET薄膜的能隙约为3.96eV。我们从PL测量获得的结果表明,该方法将有助于理解绝缘聚合物的陷阱分布和发光微机制。

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