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THE EFFECT OF COATING ON THE LEACHABILITY AND COMBUSTIBILITY OF FIRE-RETARDANT IMPREGNATED WOOD AFTER WEATHERING TEST

机译:耐候性试验后,涂层对阻燃浸渍木材的可浸性和可燃性的影响

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Recently, the consumer’s demand to use fire-retardant treated wood as an exterior use is elevatingin Japan. However, the fire-retardant chemicals are basically water soluble and they are easily leaching outby rainwater. There are few reports on weatherability and comubustibity of fire-retardant wood for outdooruse in Japan. There are also few data indicating the effects on surface coatings to prevent leaching of fireretardantchemicals. This study evaluates weatherability and combustibility of fire-retardant woods withcoatings during 2000 hours of accelerated and 18 months of natural weathering tests.As a fire-retardant, polyphosphatic carbamate was impregnated into sugi (Cryptomeria japonica)sapwood. Four coating systems (water-borne or solvent-borne, pigmented or clear, film-forming orpenetrating) were used to study their effects for preventing leaching of the chemicals.In accelerated weathering, all of the coated specimens maintained the Quasi-noncombustibleMaterial fire performance until 1000 hours, although uncoated specimen could only show the Fire-retardantMaterial performance at 250 hours. In natural weathering, coated and uncoated specimens maintainedQuasi-noncombustibility at 6 months, however the uncoated specimen’s chemical retention was thesmallest and decreased to less than 70kg/m3 at 9 months.The fire-retardants distribution was examined by SEM and x-ray microanalysis for acceleratedweathered specimens. The fire-retardant chemicals were accumulated in both cell walls and luminathroughout the wood tissues. Without coatings, the fire-retardants were leached from the surfaces. Leachingwas observed down to a depth of 150μm from the surface after 500 hours, and extended throughout thespecimen after 1000 hours of accelerated weathering. However, the fire-retardants were remained in thesamples finished with coatings even after 1000-hour weathering test.
机译:最近,消费者对使用经过阻燃处理的木材作为外部用途的需求正在上升 在日本。但是,阻燃化学品基本上是水溶性的,很容易浸出 被雨水冲刷。关于用于室外的阻燃木材的耐候性和易燃性的报道很少。 在日本使用。也很少有数据表明对表面涂层可防止阻燃剂浸出的影响 化学药品。这项研究评估了阻燃木材的耐候性和可燃性。 在加速2000小时和18个月的自然风化测试中使用。 作为一种阻燃剂,将多磷酸氨基甲酸酯浸渍到sugi(Cryptomeria japonica)中 边材。四种涂料体系(水性或溶剂型,有色或透明,成膜或 渗透性)用于研究其防止化学品浸出的作用。 在加速风化中,所有涂层样品均保持准不燃 材料防火性能可达到1000小时,尽管未镀膜的样品只能显示出阻燃性 250小时的材料性能。在自然风化下,可以保持涂层和未涂层​​的标本 在6个月时具有准不燃性,但是未涂层的标本的化学保留值是 最小,并在9个月时降至70kg / m3以下。 通过SEM和X射线显微分析检查了阻燃剂的分布 风化的标本。阻燃化学物质聚集在细胞壁和内腔中 遍及整个木质组织。没有涂料,则从表面浸出阻燃剂。浸出 在500小时后观察到从表面向下到150μm的深度,并延伸到整个 加速风化1000小时后的样品。但是,阻燃剂仍保留在 样品即使经过1000小时的耐候性测试也可以完成涂层处理。

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