首页> 外文会议>International in situ and on-site bioremediation symposium >ISCO Pilot Study of Density Driven Diffusion of NaMnO4in a Fractured Rock Environment
【24h】

ISCO Pilot Study of Density Driven Diffusion of NaMnO4in a Fractured Rock Environment

机译:破裂岩石环境中NaMnO4的密度驱动扩散的ISCO中试研究

获取原文

摘要

AECOM conducted an in situ chemical oxidation (ISCO) pilot study forthe Pennsylvania Department of Environmental Protection (PADEP) at a former platingfacility located in Upper Milford Township, Pennsylvania (Site). Located south of Allentown,Pennsylvania, the Site operated as an electroplating and polishing facility from theearly 1960s to the early 1980s. Site characterization data indicated that the primary contaminantof concern (COC), trichloroethene (TCE), has been observed at a concentration of40,000 μg/L within the weathered/fractured bedrock of the source area. Tetrachloroethylene(PCE) and degradation byproducts of TCE and PCE are present at significantly lowerconcentrations within the source area and wider dissolved plume. Elevated concentrationsof chlorinated solvents also exist in the deep portion of the fractured bedrock aquifer. Evidencesuggests that dense nonaqueous-phase liquids (DNAPLs) contained in the aquiferunderlying the source area are serving as a residual source of chlorinated solvents to thegroundwater. Former operations at the Site present the possibility of metal mobilization;however, the depth, distribution, and concentrations of the COCs lend themselves to anISCO application within the source area.The conceptual treatment approach for the pilot study utilizes the density contrast betweenthe sodium permanganate (NaMnO4) solution and groundwater, as well as, the totalvolume of liquid to be injected. A conceptual site model was developed, where the denserNaMnO4 solution achieves a radius of influence (ROI), sinks to the top of the weatheredbedrock, and ultimately travel laterally along the surface of the competent bedrock untilencountering the naturally occurring fractures within the competent bedrock. A thoroughunderstanding of overlying unconsolidated material (soils), weathered bedrock interface,and locations of primary fractures in the competent bedrock was essential in developing theconceptual site model and subsequent remedial approach.The first objective of the pilot study was to verify the connectivity of bedrock fractureswithin the source area. The second objective was to perform source control by oxidizingCOCs in situ by injecting NaMnO4 at and near the source area via existing monitoringwells and strategically located injection/monitoring wells. The oxidant was injected at theweathered bedrock interface with the potential for the oxidant to migrate downward to fractureslocated in the competent bedrock. The third objective was to utilize the pilot test datato optimize a full-scale design and gather real time treatment information regarding contaminantreductions.The pilot test has been completed over three (3) injection periods utilizing gravityflow/low pressure to deliver the NaMnO4 due to the proximity of sensitive receptors (I.e.,surface water and water supply wells). The effectiveness of each injection event for oxidiz-
机译:AECOM进行了原位化学氧化(ISCO)中试研究 宾夕法尼亚州环境保护局(PADEP)的前镀层 设施位于宾夕法尼亚州的上米尔福德镇(站点)。位于阿伦敦(Allentown)南部, 该网站是宾夕法尼亚州的电镀和抛光设施,位于美国宾夕法尼亚州 1960年代初至1980年代初。现场表征数据表明主要污染物 (COC),三氯乙烯(TCE)的浓度为 源区域的风化/断裂基岩中的浓度为40,000μg/ L。四氯乙烯 (PCE)和TCE和PCE的降解副产物的含量要低得多 源区域内浓度高,溶解羽宽。浓度升高 在裂隙基岩含水层的深部也存在氯化物溶剂。证据 表明含水层中所含的稠密非水相液体(DNAPL) 源区域下面的物质用作氯溶剂的残留源。 地下水。现场以前的作业可能会动员金属。 但是,COC的深度,分布和集中度使其适合于 源区域内的ISCO应用程序。 初步研究的概念性治疗方法利用了两者之间的密度对比 高锰酸钠(NaMnO4)溶液和地下水,以及全部 注入的液体量。开发了一个概念性的站点模型,其中 NaMnO4解决方案达到影响半径(ROI),沉入风化的顶部 基岩,最终沿主管基岩表面横向移动,直到 在主管基岩中遇到天然裂缝。彻底的 了解上覆的未固结材料(土壤),风化的基岩界面, 主管基岩中的原始裂缝的位置和位置对于开发 概念性站点模型和后续的补救方法。 初步研究的第一个目标是验证基岩裂缝的连通性 在源区域内。第二个目标是通过氧化来执行源控制 通过现有监测,通过在源区及其附近注入NaMnO4来原位生成COC 井和战略位置的注入/监测井。在 风化的基岩界面具有氧化剂向下迁移至裂缝的潜力 位于主管的基岩中。第三个目标是利用试点测试数据 优化全面设计并收集有关污染物的实时处理信息 减少。 利用重力在三(3)个注入周期内完成了先导测试 由于敏感受体的接近(例如, 地表水和供水井)。每次注射对氧化的有效性

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号