THE SYNTHESIS AND SOME CHEMICAL TRANSFORMATIONS OF ALKYLNITROAMINO-POLYNFTROMETHYL-1,3,5-TRIAZINES

摘要

The N-nitration of alkylamino-1,3,5-triazines which contain polynitromethyl group as a substituent in a system ?acetic anhydride-nitric acid? leads to the formation of alkylnitroamine derivatives of 1,3,5-triazines. Denitration of alkylnitroamino-trinitromethyl-1,3,5-triazines goes selectively on trinitromethyl group. The functional derivatives on dinitromethyl group can be synthesized on the basis of alkylnitroamino-dinitromethyl-1,3,5-triazine salts. The structure of 2-metoxy-4-methylnitroamino-6-chlorodinitromethyl-1,3,5-triazine was investigated by X-ray analysis..