Study on Multi-phase Separation of Production of Liquid Phase Oxidation of Chromite in Sub-molten Salt

摘要

As one of the key inorganic chemical industries, the chromate chemical industry has spawned extensively public concerns due to the resulted environmental pollution The cleaner production technology for chromium compounds bases on sub-molten salt medium developed by the Institute of Process Engineering, Chinese Academy of Sciences has greatly decreased the reaction temperature and energy consumption, significantly increased the utilization ratio of the chromium element, and successfully achieved the comprehensive utilization of chromite resources and zero emission of chromium-containing residue. The separation process of production is the most important components in the cleaner technology. In this work, we studied two parts: the first is the removal of SiO2, Al3+ from the system and the recycling utilization of alkali metal medium through adding Ca(OH)2 and CaO; the second is to get more pure K2CrO4 crystalloid and remove K2CO3 from KOH solution through evaporation to prepare raw material for manufacturing Cr2O3 and get 50%(wt) KOH. The results obtained show that Ca(OH)2 can remove Al3+ more than CaO and has lower caustic ratio than CaO when they were added 110% of theoretic quantity. The optimal pure K2CrO4(96%) can be gained at 45 Celsius degree in 30%KOH solution and K2CO3 in 50% KOH solution could be decreased to 3.5%(wt) at 40 Celsius degree. And then K2CO3 can be causticized with adding Ca(OH)2 to recycle potassium alkali. The impure material can be removed and suitable raw material for manufacturing Cr2O3 can be gotten and reaction medium can be also recycled in this process technology, realizing cleaner production effectively.