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MICRO AND MESOPOROUS MOLDED ACTIVATED CARBON MADE FROM RICE HUSK AND BEET SUGAR

机译:稻壳糖和甜菜糖制成的微孔和中孔模制活性炭

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Micro and mesoporous molded activated carbon was fabricated from rice husk and beet sugar. Beet sugar was added into rice husk pre-carbonized at 250°C in the form of syrup. This blend was carbonized at 600°C and then pulverized. The powder obtained was press-molded into a disc using the beet sugar syrup as a binder. The molded disc was carbonized at 875 °C and then immersed in the beet sugar syrup. The immersed disc was activated at 875°C in CO_2 for 0.5-2.5 h. The pore structure of the rice husk and beet sugar based activated carbon (RHBSAC) was analyzed in relation to bulk density. The gas activation time of 2.0 h provided the largest total pore volume and BET specific surface area (0.68 cm~3/g and 1027 m~2/g), but low bulk density (0.54 g/cm~3). RHBSAC of which activation time was 1 h was once again immersed in the beet sugar syrup and then activated in CO_2 for 1 h. This two-steps activation provided high bulk density (0.69 g/cm~3) and high micro and mesoporous structure (BET specific surface area: 943 m~2/g, total pore volume: 0.56 cm~3/g, micropore volume: 0.32 cm~3/g, mesopore volume: 0.19 cm~3/g).
机译:微和中孔模制的活性炭是由稻壳和甜菜糖制成的。将甜菜糖以糖浆的形式添加到在250°C下预碳化的稻壳中。将该共混物在600℃下碳化,然后粉碎。使用甜菜糖浆作为粘合剂将获得的粉末压制成盘。将成型的圆盘在875°C下碳化,然后浸入甜菜糖浆中。将浸没的圆盘在875°C的CO_2中活化0.5-2.5小时。分析了稻壳和甜菜糖基活性炭(RHBSAC)的孔结构与堆积密度的关系。 2.0 h的气体活化时间提供最大的总孔体积和BET比表面积(0.68 cm〜3 / g和1027 m〜2 / g),但堆积密度低(0.54 g / cm〜3)。将活化时间为1小时的RHBSAC再次浸入甜菜糖浆中,然后在CO_2中活化1小时。这两个步骤的活化提供了高的堆积密度(0.69 g / cm〜3)和高的微孔和中孔结构(BET比表面积:943 m〜2 / g,总孔体积:0.56 cm〜3 / g,微孔体积: 0.32 cm〜3 / g,中孔体积:0.19 cm〜3 / g)。

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