New Light Stabilizer Systems for TPU used in Sports and Leisure Applications

摘要

Thermoplastic Polyurethanes are prone to degradation both during processing and end-use, as a result of the combined effects of thermal-oxidative and UV light exposure. During manufacture, antioxidants are effective at preventing freeradical induced oxidation, and maintaining low color. Thermoplastic Polyurethanes based on aromatic isocyanates are generally characterized by poor light stability. Light colored and transparent TPUs used in Sports and Leisure Wear applications therefore have to be stabilized against discoloration. Thermoplastic Polyurethane makes it possible in the fields of sport and casual footwear to manufacture so called lightweights with high grade quality characteristics for very specific requirements. The chosen raw materials determine reactivity, functionality and molecular weight – all important factors which have a direct bearing on the final properties. In this way, the finished material (e.g. shoe sole) can be made rigid or flexible, highly elastic or with good shock absorbing properties, and with varying degrees of thermal stability and abrasion resistance. Finally, factors such as ageing resistance, light stability and behavior in different media, and more complex properties like grip and flexcrack resistance are important characteristics for the targeted applications. A stabilizing system for thermoplastic polyurethane generally consists of UV stabilizers, hindered amine light stabilizers and antioxidants. The focus of this paper will be outstanding initial color and improved light stability of aromatic based Thermoplastic Polyurethanes. A new solid light stabilizer blend will be introduced.