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An Alternative Method for theRemoval of Sulphur From FCC Gasoline

机译:从FCC汽油中脱硫的另一种方法

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This study is being performed as part of a graduate thesisproject at the University of Northern British Columbia. We areattempting to develop an alternative method for removing sulfurcompounds from the fluid catalytically cracked stream ofgasoline (FCC gasoline). Canada recently developed newregulations for the amount of total sulfur in fuel, as of January1st, 2005, thereby limiting the total sulfur to 30 ppmw. Thispaper reports on our work to date using a Raney-nickel typecatalyst for the removal of sulfur-containing compounds fromFCC gasoline. We will report on the successful results we haveachieved to date including experiments where temperature andreaction time were varied. Raney-type nickel is activated withan alkaline solution, then reacted with the FCC gasoline toform a nickel sulfide precipitate. Our most promising resultsindicate a 60% drop in total sulfur concentration in the treatedFCC gasoline. This reaction occurs at ambient temperatures and pressures and is currently being performed on a laboratoryscale. The samples are analyzed using UV FluorescenceSpectroscopy in order to determine total sulfur content.
机译:这项研究是研究生论文的一部分 北不列颠哥伦比亚大学的项目。我们是 试图开发另一种脱硫方法 流化床催化裂化流中的化合物 汽油(FCC汽油)。加拿大最近开发了新的 截至一月的燃料中总硫含量的法规 2005年1月1日,从而将总硫含量限制为30 ppmw。这 迄今为止,我们使用Raney镍型纸质报告 去除含硫化合物的催化剂 FCC汽油。我们将汇报我们取得的成功成果 迄今为止取得的成就,包括在温度和 反应时间各不相同。雷尼型镍被激活 碱性溶液,然后与FCC汽油反应生成 形成硫化镍沉淀。我们最有希望的结果 表明处理后的总硫浓度下降了60% FCC汽油。该反应在环境温度和压力下发生,目前正在实验室中进行 规模。使用紫外荧光分析样品 用光谱法测定总硫含量。

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