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A Portable SOFC System with Integrated Catalytic Fuel Processing

机译:具有集成催化燃料处理的便携式SOFC系统

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Global warming is thought to result from emissions largely caused by combustion reactions. If all existing burners could incorporate an SOFC, then global wanning could be much inhibited because of the improved exergy of SOFCs compared with existing catalytic burners. This paper proposes a new type of ceramic SOFC/burner which incorporates many of the innovations which are needed to improve burner performance, including catalytic combustion, premixed fuel/air, recuperation of combustion heat, recycling of reaction products, electric-ignition and electron extraction. The key problems of fuel variation and thermal shock resistance are addressed through the concept of 'reaction gradient' in which the rich sequence of oxidation reactions during combustion is spread through three extended catalytic regimes along the isothermal ceramic device. It is evident that ceramic materials such as zirconium oxide are necessary in this device to provide catalytic activity and to promote electron transfer. The conclusion is that ceramic will ultimately replace metal in SOFC/burners requiring low emissions and high exergy output.
机译:人们认为,全球变暖主要是由燃烧反应引起的排放引起的。如果所有现有的燃烧器都可以包含SOFC,那么与现有的催化燃烧器相比,由于SOFC的改进了的火用,全球排放量将受到很大的抑制。本文提出了一种新型的陶瓷SOFC /燃烧器,该燃烧器结合了提高燃烧器性能所需的许多创新,包括催化燃烧,预混合燃料/空气,燃烧热回收,反应产物的循环利用,电点火和电子提取。通过“反应梯度”的概念解决了燃料变化和抗热冲击性的关键问题,其中燃烧过程中氧化反应的丰富序列沿着等温陶瓷装置通过三个扩展的催化方式扩散。显然,在该装置中需要陶瓷材料如氧化锆以提供催化活性并促进电子转移。结论是,陶瓷将最终替代要求低排放和高火用输出的SOFC /燃烧器中的金属。

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