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Novel Glycerol-based Immobilized Liquid Membranes For Gas Separation

机译:用于气体分离的新型基于甘油的固定化液体膜

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Gas separation using facilitated transport membranes (FTM) has been extensively investigated. Major advantages of FTM over conventional polymeric membranes include higher permeabilities for reacting species like CO_2. olefins and the resultant high selectivities over nonreacting species like N_2. paraffins. This is due to the facilitating freaction mechanism in FTMs compared to the solution-diffusion mechanism in polymeric membranes. FTMs are particularly attractive at low reacting species concentrations where the driving force is very low. This is especially advantageous for removal and sequestration of carbon dioxide when it is present in low concentrations. Facilitated transport membranes include immobilized liquid membranes (ILMs) where the carrier in a Solvent, usually water, is immobilized in the pores of the membrane.
机译:使用便利的运输膜(FTM)进行气体分离已得到广泛研究。与传统的聚合物膜相比,FTM的主要优点包括更高的渗透性,可与诸如CO_2之类的物质发生反应。烯烃和对非反应物种(如N_2)的高选择性。石蜡。这是由于与聚合物膜中的溶液扩散机制相比,FTM中的促进碎裂机制所致。在驱动力非常低的低反应物种浓度下,FTM尤其有吸引力。当二氧化碳以低浓度存在时,这对于除去和隔离二氧化碳特别有利。便利的运输膜包括固定的液体膜(ILM),其中溶剂(通常是水)中的载体固定在膜的孔中。

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