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METAL ADSORPTION PROPERTIES OF PITCH-BASED ACTIVATED CARBON FIBERS MODIFIED BY HNO_3 AND NaOH

机译:HNO_3和NaOH改性沥青基活性炭纤维的金属吸附性能。

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The main aim of oxidation of the carbon surface is obtaining a more hydrophilic surface structure with a relatively large number of oxygen-containing surface groups. For other carbon-supported catalyst, the modification of carbon surface results in significant changes of the loading capacity and the catalytic properties. The formation of surface functional groups may come as a result of the direct interaction of the modifying agent during the modification of the initial precursor fiber, carbonization, and activation. The oxidative treatment of carbon materials is the frequently used method in the production of carbon based ion-exchangers . In this paper, the chemical modification of pitch-based activated carbon fibers with nitric acid is carried out in order to increase the metal adsorption capacity by inducing surface oxygen-containing groups. Another modification is conducted with sodium hydroxide in order to compare with the result of above modification.
机译:碳表面氧化的主要目的是获得具有相对较多的含氧表面基团的更亲水的表面结构。对于其他碳载催化剂,碳表面的改性导致负载能力和催化性能的显着变化。表面官能团的形成可能是由于在初始前体纤维的改性,碳化和活化过程中改性剂直接相互作用的结果。碳材料的氧化处理是生产碳基离子交换剂的常用方法。在本文中,对沥青基活性炭纤维进行了硝酸化学改性,以通过诱导表面含氧基团来提高金属吸附能力。为了与上述改性的结果比较,用氢氧化钠进行另一种改性。

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