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FLOW INSTABILITY REDUCTION OF PP THROUGH BLENDING OF EVA

机译:通过EVA共混降低PP的流动不稳定性

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Flow instabilities are often encountered during extrusion of high molecular weight Polypropylene homopolymers. Traditional techniques of flow instability reduction such as addition of fluoropolymers or compatibilizers significantly increase the cost of the finished product. During this study it was found that blending small amounts of Poly (Ethyl Vinyl Acetate) EVA into the polypropylene PP matrix eliminates melt fracture formation within a reasonable operating window, maintaining acceptable mechanical properties. A wide range of EVA concentrations was tested using capillary rheometry, microscopy and mechanical analysis. The acceptable operating window without instabilities was determined by analyzing the extrudate surface under the microscope.
机译:在高分子量聚丙烯均聚物的挤出过程中经常遇到流动不稳定性。减少流动不稳定性的传统技术,例如添加含氟聚合物或增容剂,会显着增加最终产品的成本。在这项研究中,发现将少量的聚(醋酸乙烯乙酯)EVA掺入聚丙烯PP基体中,可以消除熔体断裂的形成,并保持合理的机械性能。使用毛细管流变仪,显微镜和机械分析测试了各种EVA浓度。通过在显微镜下分析挤出物表面来确定可接受的无不稳定的操作窗口。

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