The distributions of impurities in the copper melt, the slag and the gas phase in copper flash smelting process were under study in the Guixi smelter, particularly during opoerating conditions of high oxygen enrichment with production of high grade matte. Several methods for the removal of impurities such as As, Sb and Bi in the copper smelting process were developed and implemented at the Guixi smelter. This paper described the effects of high oxygen enrichment, elevated matte grade, high temperature and high production rate on the distribution of impurities, methods adopted at the smelter for the removal of impurities, and the associated benefits in the utilization of these removal techniques which include the mathematical model for material blending, high thermal intensity operation at the flash furnace, extended converter blowing, and injection of slag modifiers consisting of Na_2CO_3 and CaO powder mixture to the converters and anode furnaces.
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