首页> 外文会议>Annual technical conference of the Society of Plastics Engineers;Technical conference of the Society of Plastics Engineers;ANTEC 2009 >EFFECT OF ORGANOCLAY ON THE MECHANICAL / THERMAL PROPERTIES OF MICROCELLULAR INJECTION MOLDED PBT-CLAY NANOCOMPOSITES
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EFFECT OF ORGANOCLAY ON THE MECHANICAL / THERMAL PROPERTIES OF MICROCELLULAR INJECTION MOLDED PBT-CLAY NANOCOMPOSITES

机译:有机粘土对微孔注射成型PBT-粘土纳米复合材料力学/热力学性能的影响

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An organically modified montmorillonite (MMT) was compounded with Polybutylene Terephthalate (PBT) in a twin-screw extruder. The organoclay PBT nanocomposites were then injection molded by conventional and microcellular methods. Nitrogen was used as the blowing agent. The effect of organoclay content, organoclay size (8 and 35 um), and speed of the screw (80 and 100 rpm) on the mechanical and thermal properties were investigated.The results showed that when the MMT content was 1.0 wt%, the nanocomposites have maximum tensile strength, wear resistance, and cell density. Moreover, the larger the particle size, the greater the tensile strength. The screw speed during compounding also affected the mechanical strength. The higher speed of the screw increased the tensile strength of the nanocomposites. The addition of MMT also helped the thermal stability of the PBT/Clay nanocomposites. The WXRD results showed that when MMT loading is 1.0 wt%, the nanocomposites have maximum d-spacing structure. TEM results showed that MMT is well dispersed on the nanocomposites at a MMT loading of 1 .0 wt%.
机译:在双螺杆挤出机中将有机改性的蒙脱石(MMT)与聚对苯二甲酸丁二酯(PBT)混合。然后通过常规方法和微孔方法将有机粘土PBT纳米复合材料注塑成型。氮气用作发泡剂。研究了有机粘土含量,有机粘土尺寸(8和35 um)以及螺杆转速(80和100 rpm)对机械和热性能的影响。 结果表明,当MMT含量为1.0重量%时,纳米复合材料具有最大的拉伸强度,耐磨性和孔密度。此外,粒径越大,拉伸强度越大。混合过程中的螺杆速度也会影响机械强度。螺杆的较高速度增加了纳米复合材料的拉伸强度。 MMT的添加还有助于提高PBT /粘土纳米复合材料的热稳定性。 WXRD结果表明,当MMT负载量为1.0 wt%时,纳米复合材料具有最大的d-间隔结构。 TEM结果显示,MMT以1.0重量%的MMT负载良好地分散在纳米复合材料上。

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