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INFLUENCE OF TRANSFORMATION OF CORROSION PRODUCTS ON CORROSION OF MILD STEEL IN SEA MUD CONTAINING ACTIVE SRB

机译:腐蚀产物的转变对含活性SRB的海泥中低碳钢腐蚀的影响

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Microbiologically influenced corrosion (MIC) is very severe corrosion for the constructions buried in sea mud environment Therefore it is of great importance to carry out the investigation of the corrosion behavior of marine steel in sea mud. In mis paper, the effect of sulfate-reducing bacteria(SRB) on corrosion behavior of mild steel in sea mud was studied by weight loss, dual compartment-cell, electronic probe microanalyzer(EPMA), transmission electron microscope(TEM) combined with energy dispersive X-ray detector (EDX) and electrochemical impedance spectroscopy(EIS). The results showed that free corrosion rate and galvanic current were influenced by the metabolic activity of SRB. In the environment of sea mud containing SRB, the original corrosion products, ferric (oxyhydr)oxide, transformed to ferrous sulfide. With the increase of the dissolved H_2S the component of the protective layer formed of FeS transformed to Fe_(1-x)S, and FeS_(1-x) later, which changed the state of the former layer and accelerated the corrosion process.
机译:微生物影响的腐蚀(MIC)对于埋在海泥环境中的建筑物来说是非常严重的腐蚀,因此,开展海藻钢在海水中的腐蚀行为的研究非常重要。通过失重,双室电池,电子探针显微分析仪(EPMA),透射电子显微镜(TEM)结合能量研究了还原硫酸盐细菌(SRB)对海泥中低碳钢腐蚀行为的影响。色散X射线检测器(EDX)和电化学阻抗谱(EIS)。结果表明,SRB的代谢活性影响自由腐蚀速率和电流。在含有SRB的海泥环境中,原始腐蚀产物三氧化二铁转化为硫化亚铁。随着H_2S溶解量的增加,FeS形成的保护层的成分转变为Fe_(1-x)S,之后转变为FeS_(1-x),改变了前一层的状态,加速了腐蚀过程。

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