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SHALE GAS PROCESSING RETROFIT OPTIONS

机译:页岩气处理改造方案

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Processing large volumes of shale gas with moderate levels of CO_2 and trace amounts of H_2S requires consideration of several technology options to optimize plant economics and operations. This paper will focus on issues to consider which allow an existing sour gas plant to modify operations to process all shale gas or a blend of existing gas and shale gas. Conventional treating of shale gas generates an acid gas stream which is mostly CO_2 with much less than one percent of H_2S. Sulfur recovery may be required to meet environmental regulations, and CO_2 could be made available for use in Enhanced Oil Recovery (EOR) operations or sequestration. The low H_2S to CO_2 concentration ratio in the feed shale gas, and the subsequently removed acid gas, challenges the typical Claus-based sulfur recovery option. It requires substantial upstream Acid Gas Enrichment (AGE) to concentrate the acid gas sufficiently to support the likely required high sulfur recovery (say >98%). Potential alternatives include acid gas injection or acid gas processing using direct oxidation, redox, chemical absorption or reaction, and biological processes. The alternative sulfur recovery processing options generate different forms of solid sulfur products, which are typically land filled, versus the sales-quality sulfur recovered from Claus SRUs. This paper will review and compare the various process options for sulfur recovery from shale gas blended with conventional gas where the H_2S levels are high enough to make scavengers uneconomical, while rejecting a CO_2 stream that can be available for EOR or sequestration.
机译:用中等水平的CO_2和痕量的H_2S处理大量页岩气需要考虑多种技术选择,以优化工厂的经济性和运营。本文将重点考虑允许现有酸性天然气厂修改操作以处理所有页岩气或现有天然气和页岩气的混合物的问题。页岩气的常规处理产生酸性气流,该酸性气流主要是CO_2,而H_2S的比例要少得多。可能需要回收硫才能满足环境法规的要求,并且可以将CO_2用于增强采油(EOR)操作或封存。原料页岩气中低的H_2S与CO_2浓度比,以及随后去除的酸性气体,对典型的基于Claus的硫回收方法提出了挑战。它需要大量的上游酸性气体富集(AGE)来充分浓缩酸性气体,以支持可能需要的高硫回收率(例如> 98%)。可能的替代方法包括使用直接氧化,氧化还原,化学吸收或反应以及生物过程的酸性气体注入或酸性气体处理。替代性的硫磺回收工艺选项会生成不同形式的固体硫磺产品,通常将其填埋,而不是从Claus SRU中回收的销售质量硫磺。本文将回顾和比较从页岩气与常规气体混合回收硫的各种工艺选择,其中H_2S含量足够高,使清除剂变得不经济,同时拒绝了可用于EOR或封存的CO_2物流。

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