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Synthesis of FER Type Zeolite in Presence of Tetrahydrofuran

机译:四氢呋喃存在下FER型沸石的合成

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Hydrothermal crystallization of FER type zeolite from a reactant of THF (tetrahydrofuran)· Na_2O·SiO_2·Al_2O_3·H_2O system was investigated. FER zeolite with high crystallinity can be prepared by spontaneous crystallization in the reactant. TG/DTG/DTA and ~(13)C MAS NMR spectra prove that THF molecules are incorporated in the pores of the zeolite. The influence of SiO_2/Al_2O_3 molar ratio, alkalinity, amount of template and reaction temperature on the synthesis of the zeolite was explored as well.
机译:研究了THF(四氢呋喃)·Na_2O·SiO_2·Al_2O_3·H_2O体系反应物对FER型沸石的水热结晶。具有高结晶度的FER沸石可以通过在反应物中自发结晶来制备。 TG / DTG / DTA和〜(13)C MAS NMR光谱证明THF分子掺入了沸石的孔中。考察了SiO_2 / Al_2O_3的摩尔比,碱度,模板量和反应温度对沸石合成的影响。

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  • 来源
  • 会议地点 Montpellier(FR);Montpellier(FR)
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    Department of Chemistry Fudan University Shanghai 200433 P. R. China Research Institute of Beijng Yanshan Petrochemical Corporation SINOPEC Beijing 102500 P. R. China;

    Center of Analysis and Measurement Fudan University Shanghai 200433 P. R. China;

    Department of Chemistry Fudan University Shanghai 200433 P. R. China;

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