首页> 外文会议>International Workshop on Fracture of Materials: Moving Forwards; 20060123-25; Sydney(AU) >Properties of Polypropylene/Carbon Nanotube Composites Compatibilized by Maleic Anhydride Grafted SEBS
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Properties of Polypropylene/Carbon Nanotube Composites Compatibilized by Maleic Anhydride Grafted SEBS

机译:马来酸酐接枝SEBS增容聚丙烯/碳纳米管复合材料的性能

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摘要

Isotactic polypropylene (PP)/carbon nanotube (CNT) composites compatibilized by maleic anhydride grafted styrene-ethylene/butylenes-styrene copolymer (MA-SEBS) were prepared by melt compunding and compression moulding. The melt compouding torque, thermal properties, dynamical mechanical behavior, mechanical and anti-static properties of the PP/CNT composites were systematically invertigated. The results indicated that MA-SEBS is an effective compatilizer for the PP/CNT composites. The melting and crsytallization temperatures (T_m and T_c), crystallinity degree (X_c) of the PP phase in PP/CNT composites increase remarkably with the CNT content. Compared with PP/CNT composites, the incorporation of MA-SEBS increases T_m, but decreases T_c, crystallization rate and X_c of PP phases in PP/MA-SEBS/CNT composites. Owing to MA-SEBS as a compatibilizer to enhance formation of a perfect percolation network, the thermal, mechanical and anti-static properties of PP/CNT are improved.
机译:通过熔融复合和压塑法制备了由马来酸酐接枝的苯乙烯-乙烯/丁烯-苯乙烯共聚物(MA-SEBS)增容的等规聚丙烯(PP)/碳纳米管(CNT)复合材料。系统地研究了PP / CNT复合材料的熔体复合转矩,热性能,动态力学行为,力学性能和抗静电性能。结果表明,MA-SEBS是PP / CNT复合材料的有效相容剂。 PP / CNT复合材料中PP相的熔融和结晶温度(T_m和T_c),结晶度(X_c)随着CNT含量的增加而显着增加。与PP / CNT复合材料相比,MA-SEBS的加入增加了T_m,但降低了PP / MA-SEBS / CNT复合材料中PP相的T_c,结晶速率和X_c。由于MA-SEBS作为增容剂可增强完美的渗流网络的形成,因此提高了PP / CNT的热,机械和抗静电性能。

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