首页> 外文会议>International Conference on Rare Earth Research and Application; 2004; >Catalytic Performance of Ce/Zr Oxides Catalysts for Soot Combustion
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Catalytic Performance of Ce/Zr Oxides Catalysts for Soot Combustion

机译:Ce / Zr氧化物催化剂对烟灰燃烧的催化性能

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摘要

Catalytic performances of a series Ce/Zr oxides(Ce_x Zr_(1-x)O_2) for soot combustion were investigated. The catalytic activities for soot combustion were affected by both the Ce/Zr ratio and the oxygen storage capability of Ce/ Zr oxides. O_2-TPD and TG-DTA results indicate that Ce_xZr_(1-x)O_2 can release its lattice oxygen continuously and promote soot combustion even no oxygen occurs in the reaction atmosphere. Among these Ce/Zr oxides, Ce_(0.5)Zr_(0.5) O_2 has the best catalytic activity, and the ignition temperature of soot combustion was about 410℃, which is close to the practical exhaust temperature of the diesel engine.
机译:研究了一系列Ce / Zr氧化物(Ce_x Zr_(1-x)O_2)对烟灰燃烧的催化性能。 Ce / Zr比和Ce / Zr氧化物的储氧能力均会影响烟灰燃烧的催化活性。 O_2-TPD和TG-DTA结果表明Ce_xZr_(1-x)O_2可以连续释放其晶格中的氧并促进烟尘燃烧,即使在反应气氛中没有发生氧。在这些Ce / Zr氧化物中,Ce_(0.5)Zr_(0.5)O_2具有最佳的催化活性,烟尘燃烧的着火温度约为410℃,接近柴油机的实际排气温度。

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