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Effect of Particle Size on the Debinding of PIM Parts

机译:粒度对PIM零件脱脂的影响

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摘要

It has been generally accepted that the debinding rate of powder injection molded (PIM) parts can be improved when coarse powders are used due to the larger pore size present in the compact. But, little experimental evidence has been reported. This study compares the solvent and thermal debinding rates of PIM compacts prepared from small and large particles. The weight losses during solvent and thermal debinding on specimens that are prepared from classified powders show that the particle size has little effect. Although the mercury porosimeter shows that larger pore channels are present in coarse powder compacts, their debinding rates are not enhanced. It is suggest that the solvent debinding rate is controlled by the diffusion of the soluble binder in the solvent and the amount of the binder/particle interface area. In the case of the thermal debinding, the decomposition rate of the backbone binder is the rate-controlling step.
机译:人们普遍认为,由于成形体中存在较大的孔径,使用粗粉时,可以提高粉末注射成型(PIM)零件的脱脂率。但是,几乎没有实验证据的报道。这项研究比较了由小颗粒和大颗粒制备的PIM压块的溶剂和热脱脂率。由分级粉末制备的样品在溶剂和热脱脂过程中的重量损失表明,粒径影响不大。尽管水银孔隙率仪显示出较大的孔道存在于粗粉块中,但其脱脂率并未提高。建议通过溶剂中可溶性粘合剂的扩散和粘合剂/颗粒界面面积的量来控制溶剂的脱脂率。在热脱脂的情况下,主链粘合剂的分解速率是速率控制步骤。

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