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Application of porous alumina formed in selenic acid solution for nanostructures investigation via Raman spectroscopy

机译:硒酸溶液中形成的多孔氧化铝在拉曼光谱研究中的应用

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Applicability of porous anodic alumina formed in selenic acid based electrolyte as the matrix for formation and Raman characterization of nanomaterials is investigated. For that, Raman spectra of nanostructured CdS layers deposited on top of porous alumina matrices are obtained. These spectra were compared with the ones, registered for the composites prepared using the commonly used matrix formed in oxalic acid solution. It is shown that application of porous alumina matrix formed in selenic acid electrolyte afford to detect the peaks corresponding to the CdS layers even at small amounts of CdS. It happens due to the absence of luminescence background in such matrix, which exists in matrices produced in organic acid electrolytes, for example, in oxalic acid.
机译:研究了硒酸基电解质中形成的多孔阳极氧化铝作为纳米材料的形成和拉曼表征的基质的适用性。为此,获得了沉积在多孔氧化铝基质顶部的纳米结构化CdS层的拉曼光谱。将这些光谱与通过使用草酸溶液中形成的常用基质制备的复合材料的光谱进行比较。结果表明,即使在少量的CdS下,使用硒酸电解质中形成的多孔氧化铝基质也能检测到与CdS层相对应的峰。发生这种情况是由于在这种基质中不存在发光背景,该背景存在于有机酸电解质中产生的基质中,例如草酸中。

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