首页> 外文会议>International Conference on Continuous Casting of Non-Ferrous Metals; 20051114-16; Neu-Ulm(DE) >Dendrite Coarsening and Embrittlement in Continuously Cast Tin Bronzes
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Dendrite Coarsening and Embrittlement in Continuously Cast Tin Bronzes

机译:连铸锡青铜的枝晶粗化和脆化

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Coarsening of dendrites occurs when heat removal drops suddenly after the formation of solid shell. This change in heat extraction can be caused either by slow casting speed or external disturbance in cooling system. Even if the increase in alloying elements favor coarsening, cooling rate determines the final dendrite arm spacing. Formation of the surface segregation is influenced by all process variables - directly on tin and phosphorous content and indirectly on cooling rate. Change in the dendritic length scale is required to obtain severe surface segregation. Coarsening is not sufficient condition alone to significantly reduce the elongation. Presence of the brittle constituent is also required. The cooling rate has more pronounced impact on dendrite arm spacing than on the segregation behavior. It was shown that in spite of the cooling rate, tin segregates in samples containing 8 or 10 wt.% Tin between the dendrites with the same final composition leading to formation of (α+δ) eutectoid. At low tin compositions brittle eutectoid does not form even with very high cooling rate.
机译:当固体壳形成后,热量去除突然下降时,树枝状晶体就会粗化。热量提取的这种变化可能是由于铸造速度缓慢或冷却系统的外部干扰引起的。即使合金元素的增加有利于粗化,冷却速度也决定了最终枝晶臂间距。表面偏析的形成受所有工艺变量的影响-直接影响锡和磷的含量,间接影响冷却速率。需要改变树突长度尺度以获得严重的表面偏析。单独进行粗化还不足以显着降低延伸率。还需要存在脆性成分。冷却速率对枝晶臂间距的影响比对偏析行为的影响更大。结果表明,尽管冷却速度快,但是在最终成分相同的树枝状晶体之间,锡仍偏析在含有8或10 wt%锡的样品中,导致形成(α+δ)共析物。在低锡含量下,即使以很高的冷却速度也不会形成脆性的共析物。

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