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A High Temperature Shape Memory Alloy Sensor for Combustion Monitoring and Control

机译:用于燃烧监测和控制的高温形状记忆合金传感器

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Innovations in the use of thin film SMA materials have enabled the development of a harsh environment pressure sensor useful for combustion monitoring and control. Development of such active combustion control has been driven by rising fuel costs and environmental pressures. Active combustion control, whether in diesel, spark ignited or turbine engines requires feedback to the engine control system in order to adjust the quantity, timing, and placement of fuel charges. To be fully effective, sensors must be integrated into each engine in a manner that will allow continuous combustion monitoring (turbine engines) or monitoring of each discrete combustion event (diesel and SI engines). To date, the sensors available for detection of combustion events and processes have suffered from one or more of three problems: 1) Low sensitivity: The sensors are unable to provide and adequate signal-to-noise ratio in the high temperature and electrically noisy environment of the engine compartment. Attempts to overcome this difficulty have focused on heat removal and/or temperature compensation or more challenging high temperature electronics. 2) Low reliability: Sensors and/or sensor packages have been unable to withstand the engine environment for extended periods of time. Issues have included gross degradation and more subtle issues such as migration of dopants in semiconductor sensor materials. 3) High cost: The materials that have been used, the package concepts employed, and the required support electronics have all contributed to the high cost of the few sensor systems available. Prices have remained high due to the limited demand associated with the poor reliability and the high price itself. Ternary titanium nickel alloys, with platinum group metal substitution for the nickel, are deposited as thin films on MEMS-based diaphragms and patterned to form strain gages of a standard metal film configuration. The strain induced phase transformation of the SMA is used as a natural signal enhancement. These sensors are maintained at a temperature just in excess of the austenite finish temperature (A_f). When the diaphragm is deformed by an applied pressure, the film undergoes the reversible martensite phase transformation. The fraction of the austenite transformed to martensite is a fraction of the applied pressure. The large difference in the resistivity of the two phases results in a very sensitive strain gage, and hence a pressure sensor with a very high gage factor. The combination of the thin film and the fact that the transformation is strain induced (rather than thermally induced) results in a sensor with very high response rate. In fact, the response rate of the sensor has been shown to be strictly a function of the mechanical response of the diaphragm. Unlike other sensor systems, the temperature of the SMA sensor is controlled above the temperature of the local environment. By controlling above the temperature of the environment, the sensor is largely immune to temperature fluctuations that can affect the response of other sensors. This technology has been demonstrated for a variety of target temperature regimes and a variety of pressure regimes. Sensor design and testing to date has ranged from 180C to > 500C; and design pressures of 50 to 3500 psi, with higher pressures achievable. Characterization has included analysis of the response rate, the temperature sensitivity, reliability, and the effect of gross alloy changes. Sensor performance has also been evaluated in a diesel engine test cell. Ongoing work includes the sensitivity to minor composition changes, sensitivity to film thickness, and extended reliability and engine testing.
机译:薄膜SMA材料的使用创新已经开发出可用于燃烧监测和控制的恶劣环境压力传感器。这种主动燃烧控制的发展已受到燃料成本和环境压力上升的推动。主动燃烧控制,无论是柴油发动机,火花点火发动机还是涡轮发动机,都需要反馈至发动机控制系统,以便调节加油量,正时和位置。为了完全有效,传感器必须以允许连续燃烧监控(涡轮发动机)或监控每个离散燃烧事件(柴油和SI发动机)的方式集成到每个引擎中。迄今为止,可用于检测燃烧事件和过程的传感器受到以下三个问题中的一个或多个的困扰:1)低灵敏度:在高温和电噪声环境中,传感器无法提供足够的信噪比发动机室的克服这一困难的尝试集中在除热和/或温度补偿或更具有挑战性的高温电子设备上。 2)可靠性低:传感器和/或传感器套件无法长时间承受发动机环境。问题包括严重退化和更细微的问题,例如半导体传感器材料中掺杂剂的迁移。 3)高成本:所使用的材料,所采用的包装概念以及所需的支持电子设备,均导致了少数传感器系统的高成本。由于可靠性差和价格高昂带来的需求有限,价格一直居高不下。用铂族金属替代镍的三元钛镍合金以薄膜形式沉积在基于MEMS的膜片上,并进行构图以形成标准金属膜配置的应变计。 SMA的应变诱导相变被用作自然信号增强。这些传感器的温度保持在刚好超过奥氏体终点温度(A_f)的温度。当隔膜在施加的压力下变形时,薄膜会发生可逆马氏体相变。转变成马氏体的奥氏体分数是所施加压力的分数。两相电阻率的巨大差异导致应变计非常灵敏,因此压力传感器的应变系数也很高。薄膜的结合以及变形是由应变引起(而不是热引起)的事实共同导致传感器具有很高的响应率。实际上,已经证明传感器的响应速度严格取决于膜片的机械响应。与其他传感器系统不同,SMA传感器的温度控制在局部环境温度以上。通过控制环境温度以上的温度,该传感器在很大程度上不受温度波动的影响,温度波动会影响其他传感器的响应。已经证明该技术可用于多种目标温度范围和多种压力范围。迄今为止,传感器的设计和测试范围为180C至> 500C。设计压力为50至3500 psi,并且可以达到更高的压力。表征包括响应速度,温度敏感性,可靠性和合金总变化影响的分析。传感器性能也已在柴油发动机测试单元中进行了评估。正在进行的工作包括对微小成分变化的敏感性,对膜厚度的敏感性以及扩展的可靠性和发动机测试。

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