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Gold-Cobalt Deposited on Titania Nanotubes as Anode Catalyst for Direct Borohydride Fuel Cells

机译:沉积在二氧化钛纳米管上的金钴作为直接硼氢化物燃料电池的阳极催化剂

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摘要

In the present work gold-cobalt catalysts deposited on titania nanotubes surface (denoted as AuCo/TiO_2-NTs) are studied as possible anode materials for direct borohydride/hydrogen peroxide fuel cells (DBHPFCs). The fuel cell measurements are performed in the 25 - 55 ℃ temperature range on a lab-scale direct alkaline NaBH_4-H_2O_2 single fuel cell. Polarization curves are recorded to evaluate the fuel cell performance using each prepared anode catalyst. It has been determined that the peak power density values are in the range from 87 to 102mWcm~(-2) on the Co/TiO_2-NTs catalyst and from 163 to 283 mWcm~(-2) on the AuCo/TiO_2-NTs catalysts with Au loadings ranging from 10 to 60 μg_(Au) cm~(-2).
机译:在本工作中,研究了沉积在二氧化钛纳米管表面的金-钴催化剂(表示为AuCo / TiO_2-NTs)作为直接硼氢化物/过氧化氢燃料电池(DBHPFC)的可能阳极材料。在实验室规模的直接碱性NaBH_4-H_2O_2单燃料电池上,在25-55℃的温度范围内进行燃料电池测量。记录极化曲线以评估使用每种制备的阳极催化剂的燃料电池性能。已经确定,在Co / TiO_2-NTs催化剂上的峰值功率密度值在87至102mWcm〜(-2)的范围内,在AuCo / TiO_2-NTs催化剂上的峰值功率密度值在163至283mWcm〜(-2)的范围内。 Au的负载量为10至60μg_(Au)cm〜(-2)。

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  • 会议地点 San Diego(US)
  • 作者单位

    Center of Physics and Engineering of Advanced Materials, Instituto Superior Tecnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal;

    Center for Physical Sciences and Technology, A. Gostauto 9, LT-01108, Vilnius, Lithuania;

    Center for Physical Sciences and Technology, A. Gostauto 9, LT-01108, Vilnius, Lithuania;

    Center for Physical Sciences and Technology, A. Gostauto 9, LT-01108, Vilnius, Lithuania;

    Center for Physical Sciences and Technology, A. Gostauto 9, LT-01108, Vilnius, Lithuania;

    Center for Physical Sciences and Technology, A. Gostauto 9, LT-01108, Vilnius, Lithuania;

    Center for Physical Sciences and Technology, A. Gostauto 9, LT-01108, Vilnius, Lithuania;

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