Towards the Electrolytic Oxide Reduction (EOR) of PuO2: Mitigating Side Reactions in the Cerium System

摘要

In conclusion, thermodynamic studies andelectrochemical experiments have allowed for theidentification and characterization of side reactions in theelectrolytic oxide reduction of ceria. Results from thesestudies have been used to optimize operating parameters, inorder to mitigate the effects of side reactions, and ensure amore complete and efficient EOR process. Results fromceria bulk electrolysis experiments with mitigationstrategies in place will be presented. These results will beused to guide initial plutonium EOR experiments; theseresults will also be presented.