SYNTHESIS AND STRUCTURE OF NEW PHOSPHORILATED METHANOFULLERENES WITH CARBONYL GROUPS

机译：新型带羰基的磷酸化甲基富勒烯的合成与结构

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New phosphorilated methanofullereties containing carbonyl or carbonyl and acetal group were synthesized by the reaction of bromocarbonyl phosphonates and fullerene C_(60) in the presence of bases. Structure of new compounds were established by spectroscopic methods and mass-spectra MALDI TOF. Electrochemical properties of new synthesized methanofullerenes were studied.

机译：在碱存在下，通过溴代羰基膦酸酯与富勒烯C_（60）反应，合成了新的含羰基或羰基与缩醛基的磷酸化甲基富勒烯基。通过光谱方法和质谱MALDI TOF建立了新化合物的结构。研究了新合成的甲基富勒烯的电化学性能。

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《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.196-199|共4页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
Gubskaya V.P.; Sibgatullina F.G; Nuretdinov I.A.; Yanilkin V.V.; Azancheev N.M.;
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A.E.Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov str.8, 420088 Kazan, Russia;

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正文语种 eng
中图分类无机高分子化合物（高聚物）;
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1. Metallophane Structures Based on Bis(phosphorilated) dihydroxynaphthalenes and -anthracenes [J] . P. V. Slitikov, A. V. Petrov, E. N. Rasadkina Russian Journal of Coordination Chemistry . 2007,第4期

机译：基于双（磷酸化）二羟基萘和蒽的金属电话结构
2. Continuous flow synthesis of methanofullerenes in microstructured reactors: A kinetic study [J] . Silvestrini S., Dalle Nogare D., Carofiglio T., European journal of organic chemistry . 2011,第28期

机译：在微结构化反应器中连续流动合成甲烷富勒烯的动力学研究
3. Synthesis, structure and biological activity of nitroxide malonate methanofullerenes [J] . Valentina P. Gubskaya, Lucia Sh. Berezhnaya, Aidar T. Gubaidullin, Organic & biomolecular chemistry . 2007,第6期

机译：一氧化二氮丙二酸甲烷富勒烯的合成，结构和生物活性
4. SYNTHESIS AND STRUCTURE OF NEW PHOSPHORILATED METHANOFULLERENES WITH CARBONYL GROUPS [C] . Gubskaya V. P., Sibgatullina F. G., Nuretdinov I. A., International symposium on fullerenes, nanotubes, and carbon nanoclusters . 2003

机译：用羰基新磷酸甲烷烃的合成与结构
5. Synthesis, characterization, and reactivity of titanocene cyclic organohydroborates; synthesis, spectroscopic studies, and structures of lanthanide(II)-cobalt carbonyl complexes. [D] . Plecnik, Christine E. 2003

机译：钛茂环有机硼酸酯的合成，表征和反应性；镧（II）-羰基钴配合物的合成，光谱研究和结构。
6. Polymerization Isomerism in Co-M (M = Cu Ag Au) Carbonyl Clusters: Synthesis Structures and Computational Investigation [O] . Cristiana Cesari, Beatrice Berti, Francesco Calcagno, 2021

机译：Co-M（m = CuAgAu）羰基簇中的聚合异构性：合成结构和计算调查
7. Figure 14: (A) Distribution of carbonyl (red) compared to the distribution of other compounds (cyan) in a 65 × 50 µm area of the sample. This area was measured in 0.1 µm steps. A layer of skin, identified by the yellow rectangle and predominantly composed of carbonyl, can be seen diagonally at the top-left corner of the image. The white arrow points towards the top of the skin. The red box represents the area detailed in (B). (B) Carbonyl (288.5 eV) map of the area within the red rectangle depicted in (A). The map covers an area of 20 × 20 µm of the sample in steps of 0.1 µm. The scale bar is 2 µm. Dark areas correspond to the presence of carbonyl (the data were collected with the detector in X-ray absorption mode). The yellow rectangle highlights a carbonyl layer which seems to be organized in smaller substructures, with three of them delineated by the white circles. (C) Elemental mapping of carbon (red), calcium (blue) and iron (green) of one of the substructures indicated by the white arrow in (B). [O] . -1

机译：图14：（a）与样品的65×50μm面积中的其他化合物（青色）的分布相比，羰基（红色）分布。该区域以0.1μm的步骤测量。由黄色矩形识别并主要由羰基构成的皮肤层可以在图像的左上角对角线地看到。白色箭头指向皮肤的顶部。红色框表示（b）中详述的区域。（b）（a）所示的红色矩形内区域内的区域的羰基（288.5 ev）图。该地图覆盖在0.1μm的步长的20×20μm的面积。秤条是2μm。暗区对应于羰基的存在（用X射线吸收模式用探测器收集数据）。黄矩形突出显示似乎在较小的子结构中组织的羰基层，其中三个被白色圆圈描绘。（c）由（b）中的白色箭头所示的一个子结构的碳（红色），钙（蓝色）和铁（绿色）的元素映射。
8. Chemistry of the Metal Carbonyls. Part 78. Synthesis and X-Ray Crystal Structures of (NiOs3(mu-H)2(mu-CO)2(CO)8(PPh3)2) and (Os3Rh-(mu-H)2(acac)(CO)10) (acac = Acetylacetonate) [R] . Farrugia, L. J., Howard, J. A. K., Mitrprachachon, P., 1980

机译：金属羰基化学。部分78.（NiOs3（mu-H）2（mu-CO）2（CO）8（pph3）2）和（Os3Rh-（mu-H）2（acac）（CO）的合成和X射线晶体结构10）（acac =乙酰丙酮酸盐）

SYNTHESIS AND STRUCTURE OF NEW PHOSPHORILATED METHANOFULLERENES WITH CARBONYL GROUPS

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