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Oxidation and Corrosion Behaviour of High-Alloyed Steels Basedon HCx Steel

机译:基于HCx钢的高合金钢的氧化和腐蚀行为

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HCx(R) PM stainless steels were designed for applications where high wear and corrosionrnresistance are required, as the microstructure after sintering is formed by a homogeneousrndistribution of chromium-rich carbides in a stainless steel matrix. This material was diluted orrnmixed with powders of two stainless steels, one ferritic (AISI 430) and the other onernaustenitic (AISI 316), to improve its processability and properties. The corrosion resistance ofrnthis type of steel is an interesting property to study since it is probably influenced by therncarbide content dispersed in the stainless steel matrix. The corrosion resistance of allrndeveloped materials was evaluated by potenciodynamic polarization, taking as a referencernthe behaviour of the base material. The measurements were carried out after differentrnimmersion times in an aqueous NaCl solution at room temperature. Potentiodynamic testsrnyield information on kinetic aspects of the corrosion process through metallic materialrnpolarisation processes. This technique allows the determination of the corrosion potentialrn(Ecorr), the pitting nucleation potential (Enp) and the potential range where the material isrnpassive to electrochemical corrosion (Enp-Ecorr). The oxidation resistance was studied byrnheating in air at different temperatures, up to 800 ℃, during 10 days, and evaluating the gainrnmass. In both cases a microstructural study helps to understand the mechanisms involved.
机译:HCx(R)PM不锈钢专为要求高耐磨性和耐腐蚀性的应用而设计,因为烧结后的微观组织是由富铬碳化物在不锈钢基体中的均匀分布形成的。将该材料与两种不锈钢的粉末稀释或混合,一种是铁素体(AISI 430),另一种是奥氏体(AISI 316),以提高其可加工性和性能。这种类型的钢的耐腐蚀性是值得研究的有趣特性,因为它可能受分散在不锈钢基体中的碳化物含量的影响。通过电位动力学极化评估所有显影材料的耐腐蚀性,并以基材的性能为参考。在室温下在NaCl水溶液中浸没不同的时间后进行测量。电位动力学测试通过金属材料极化过程提供了有关腐蚀过程动力学方面的信息。这项技术可以确定腐蚀电势(Ecorr),点蚀成核电势(Enp)和材料对电化学腐蚀不敏感的电势范围(Enp-Ecorr)。通过在空气中在高达800℃的不同温度下加热10天来研究其抗氧化性,并评估其增益质量。在这两种情况下,微结构研究都有助于理解所涉及的机制。

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