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IMPROVEMENT OF ELECTROCHEMICAL PERFORMANCE OF SOFC COMPOSITE ELECTRODE FORMED BY EPD

机译:EPD制备的SOFC复合电极的电化学性能的改进

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It is well known that solid oxide fuel cells (SOFCs) are the next-gen hydrogen fueled power generator, because of their high energy conversion efficiency and fuel adjustability. In order to achieve high electrical performance of SOFC, the lowering of the overpotentials of both electrodes, cathode and anode, is indispensable as well as the lowering of ohmic resistance of electrolyte. Up to date, much effort has been paid for developing electrode material with low overpotential. For instance, perovskite-type oxide with high electronic and oxide-ionic conductivities [1] and Ni-YSZ cermet with highly active Ni catalyst [2] are commonly used as cathode and anode of SOFCs, respectively. We previously succeeded in forming double layer cathodes consisting of LSM-YSZ as the active layer and LSM (La_(0.8)Sr_(0.2)MnO_3) as the current collecting layer (LSM-YSZ/LSM) by electrophoretic deposition (EPD) technique [3]. In the present study, EPD method was applied to fabricate anode and cathode of SOFCs and the resulting cell was evaluated in SOFC performance.
机译:众所周知,由于固体氧化物燃料电池(SOFC)具有高能量转换效率和燃料可调节性,因此是下一代氢燃料发电器。为了获得SOFC的高电性能,必不可少的是降低阴极和阳极这两个电极的过电势,以及降低电解质的欧姆电阻。迄今为止,已经为开发低过电位的电极材料付出了很多努力。例如,具有高电子和氧化物离子电导率的钙钛矿型氧化物[1]和具有高活性Ni催化剂的Ni-YSZ金属陶瓷[2]通常分别用作SOFC的阴极和阳极。我们先前通过电泳沉积(EPD)技术成功地形成了由LSM-YSZ作为活性层和LSM(La_(0.8)Sr_(0.2)MnO_3)作为集流层(LSM-YSZ / LSM)组成的双层阴极[ 3]。在本研究中,采用EPD方法制造SOFC的阳极和阴极,并对所得电池的SOFC性能进行了评估。

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