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Polystyrene/Plasma Treated Clay Nanocomposite

机译:聚苯乙烯/等离子处理的粘土纳米复合材料

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摘要

One of weak point of PS/clay nanocomposite is the lack of interfacial adhesion between clay and polystyrene matrix. In this research, the radical sites on the clay surface were induced via the plasma technique. The optimum condition for this process was investigated and used to treat bentonite before grafting styrene on clay structure. The increase of basel-spacing of clay was not noticeable from XRD spectra, but the FT-IR spectra showed characteristic peak of polystyrene implied that the styrene grafting was occurred on the outer surface of the clay. The impact strength is quite improved, especially for the higher ratio of styrene/clay during the grafting step.
机译:PS /粘土纳米复合材料的弱点之一是粘土与聚苯乙烯基体之间缺乏界面粘合。在这项研究中,通过等离子体技术诱导了粘土表面的自由基位点。研究了该工艺的最佳条件,并将其用于在粘土结构上接枝苯乙烯之前处理膨润土。 XRD谱图未见粘土基距的增加,但FT-IR谱图显示聚苯乙烯的特征峰,表明苯乙烯接枝发生在粘土的外表面。冲击强度得到了相当大的改善,尤其是在接枝步骤中苯乙烯/粘土比例较高的情况下。

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