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Design of Protective Coatings for Glass Lens Molding

机译:玻璃镜片成型保护膜的设计

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摘要

The glass molding process is considered to have a great potential for the mass production of aspherical glass lenses with high precision and low cost. However, glass molding has a serious problem of mold sticking with glass which needs to be resolved. This research investigates the interface reaction between glass and mold by high temperature wetting experiment, which provides the reference for the designing anti-stick coatings. The SUMITA K-PSK200 optical glass gobs with low Tg were used in this study. The influence of operation temperature, ambient gas, substrate materials, and thin film composition on wettability of glass at high temperature were studied. The results show that the higher the temperature, the smaller the wetting angle between glass gob and substrate could be observed. This indicates that severe interface chemical reaction occured and resulted in the loss of transparency in glass appearance. The wetting experiment in nitrogen ambient improved the sticking situation. The combination of chemically stable substrates and coatings, such as Sapphire (substrate) / GaN (film) and Glass (substrate) / Al_2O_3 (film) can achieve the best anti-stick propose. The precious metal films, such as Pt, Ir, coated on the ceramic substrates can effectively reduce the interface reaction between the glass and substrates.
机译:玻璃模制工艺被认为具有以高精度和低成本大量生产非球面玻璃透镜的巨大潜力。但是,玻璃成型存在严重的玻璃粘模问题,需要解决。本研究通过高温润湿实验研究了玻璃与模具之间的界面反应,为设计防粘涂料提供了参考。本研究使用低Tg的SUMITA K-PSK200光学玻璃料滴。研究了工作温度,环境气体,基底材料和薄膜组成对玻璃在高温下的润湿性的影响。结果表明,温度越高,玻璃料滴与基体之间的润湿角越小。这表明发生了严重的界面化学反应并导致玻璃外观透明性的损失。在氮气环境中的润湿实验改善了粘附情况。化学稳定的基材和涂层的结合,例如蓝宝石(基材)/ GaN(薄膜)和玻璃(基材)/ Al_2O_3(薄膜),可以达到最佳的防粘性能。涂覆在陶瓷基板上的贵金属膜(例如Pt,Ir)可以有效地减少玻璃与基板之间的界面反应。

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