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Development of the electrospun nanofiber media for filtration application: Effect of Moisture

机译:用于过滤应用的电纺纳米纤维介质的开发:水分的影响

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摘要

In recent years, many researchers have studied and developed the nanofibers which have a large specific surface area and a small pore size. The polymer nanofibers are being used or finding uses in filtration, biomedical applications including wound dressings as structural elements in artificial organs, and reinforced composites. Thus these special needs have stimulated recent studies and renewed interest in the process, quantitative technical and scientific information regarding process and product characterization are limited. Conventional spinning processes depend on pressure driven extrusion of a viscous polymer and produce fibers which are typically in the range from 10 to 500 μm diameters. The electrospinning can allow producing and encouraging the utilization of nanofibers. When an electric field is applied to the solution, the suspended drop gets distorted and starts stretching to form a Taylor cone. The distortion is caused by a balance of the repulsive forces induced on the drop due to the charge distribution and the surface tension of the liquid. When the voltage reaches a critical value, the electric force overcomes the surface tension of the deformed drop of the suspended polymer solution formed on the tip of the syringe, and a jet is produced. A jet travels through the air, the solvent evaporates leaving behind polymer fibers to be collected on an electrically grounded target. The surface morphology of e-spun fiber is affected by many variables that involve polymer concentration, applied voltage, spinning distance, air friction, gravity and ambient parameters. This study shows the effect of polymer concentration and relative humidity on the microstructures of the e-spun Polystyrene (PS) fiber.
机译:近年来,许多研究人员研究和开发了具有大的比表面积和小的孔径的纳米纤维。聚合物纳米纤维在过滤,生物医学应用(包括在医用器官中用作结构成分的伤口敷料)和增强复合材料中正在使用或正在寻找用途。因此,这些特殊需求激发了最近的研究,并对该工艺产生了新的兴趣,有关工艺和产品特性的定量技术和科学信息受到限制。常规的纺丝工艺取决于压力驱动的粘性聚合物的挤出并产生通常直径在10至500μm范围内的纤维。静电纺丝可以允许生产和促进纳米纤维的利用。当电场施加到溶液上时,悬浮的液滴变形并开始拉伸形成泰勒锥。变形是由于电荷分布和液体的表面张力而在液滴上引起的排斥力平衡引起的。当电压达到临界值时,电力克服了形成在注射器尖端上的悬浮聚合物溶液变形液滴的表面张力,并产生了射流。射流穿过空气,溶剂蒸发,留下聚合物纤维,将其收集在电接地的靶上。电纺纤维的表面形态受到许多变量的影响,这些变量涉及聚合物浓度,施加电压,纺丝距离,空气摩擦,重力和环境参数。这项研究显示了聚合物浓度和相对湿度对电纺聚苯乙烯(PS)纤维微观结构的影响。

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  • 来源
  • 会议地点 New Orleans LA(US);New Orleans LA(US)
  • 作者单位

    Center for Advanced Materials, Department of Chemical Engineering, University of Massachusetts, Lowell, MA 01854;

    Center for Advanced Materials, Department of Chemical Engineering, University of Massachusetts, Lowell, MA 01854;

    Center for Advanced Materials, Department of Chemical Engineering, University of Massachusetts, Lowell, MA 01854;

    Department of Mechanical Engineering, Pusan National University, Busan, South Korea;

    Department of Mechanical Engineering, Pusan National University, Busan, South Korea;

    Department of Mechanical Engineering, Pusan National University, Busan, South Korea;

    Department of Mechanical Engineering, Pusan National University, Busan, South Korea;

    Department of Mechanical Engineering, Pusan National University, Busan, South Korea;

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  • 正文语种 eng
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