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The Ceramic Waste Form Process at Idaho National Laboratory

机译:爱达荷州国家实验室的陶瓷废物形成过程

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The treatment of spent nuclear fuel for disposition using an electrometallurgical technique results in two high-level waste forms: a ceramic waste form (CWF) and a metal waste form. Reactive metal fuel constituents, including all the transuranic metals and the majority of the fission products remain in the salt as chlorides and are processed into the CWF. The solidified salt is containerized and transferred to the CWF process where it is ground in an argon atmosphere. Zeolite 4A is ground and then dried in a mechanically-fluidized dryer. The salt and zeolite are mixed in a V-mixer and heated to 500 ℃ to occlude the salt into the structure of the zeolite. The salt-loaded zeolite is cooled, mixed with borosilicate glass frit, and transferred to a crucible, which is placed in a furnace and heated to 925 ℃. During this process, known as pressureless consolidation, the zeolite is converted to the final sodalite form and the glass thoroughly encapsulates the sodalite, producing a dense, leach-resistant final waste form.
机译:使用电冶金技术处理废核燃料进行处置会产生两种高级废物形式:陶瓷废物形式(CWF)和金属废物形式。包括所有超铀金属和大多数裂变产物在内的活性金属燃料成分以氯化物的形式保留在盐中,并被加工成CWF。将固化的盐装箱并转移到CWF工艺中,在氩气中进行研磨。研磨沸石4A,然后在机械流化干燥器中干燥。将盐和沸石在V型混合器中混合,并加热到500℃,使盐吸附到沸石的结构中。将装有盐的沸石冷却,与硼硅酸盐玻璃粉混合,然后转移到坩埚中,将其放入炉中并加热至925℃。在这一过程中,被称为无压固结,将沸石转变为最终的方钠石形式,并且玻璃彻底包裹了方钠石,从而产生了致密的,耐浸提的最终废物形式。

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