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A Comparison of Single-Wall carbon Nanotube Production Using Continuous Wave and Pulsed Laser Vaporization

机译:连续波和脉冲激光汽化生产单壁碳纳米管的比较

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We have produced single-wall carbon nanotubes (SWNTs) by Nd:Yag laser vaporizationof porous cobalt-nickel/graphite targets for the first time without applying external heat to the target. Both continuous wave (c.w.) and pulsed laser-techniques were explored. In the pulsed experiments, the energy density per pulse was varied between 0.12 and 0.62 J/cm~2 and pulse rates ranged from 24 kHz down to 3 kHz corresponding to average powers of 25.5 to16 W. Continuous wave experiments were conducted at average powers which corresponded to those measured for each fo the pulsed runs. An additional run at 30W was also performed. A rigorous method developed for the anlaysis of transmission electron microscopy (TEM) images was used to estimate SWNT content in the laser-generated carbon samples. The pulsed and continuous wave processes both prodcued a linear increase in SWNT content with increasing average power. These resutls are not intuitive for the pulsed laser-production since a higher average power corresponds to a lower peak pulse power. In fact, a pulsed run with the maximum pulse energy of 0.62 J/cm~2 (3 kHz, 16W), produced no detectable SWNTs. A maximum SWNT content of 78
机译:我们首次通过Nd:Yag激光汽化多孔钴-镍/石墨靶制备了单壁碳纳米管(SWNT),而没有向靶施加外部热量。探索了连续波(c.w.)和脉冲激光技术。在脉冲实验中,每个脉冲的能量密度在0.12至0.62 J / cm〜2之间变化,脉冲频率范围从24 kHz降至3 kHz,对应于25.5至16 W的平均功率。连续波实验以平均功率进行对应于每个脉冲运行所测得的值。还进行了30W的额外运行。为分析透射电子显微镜(TEM)图像而开发的一种严格方法用于估算激光生成的碳样品中的SWNT含量。脉冲和连续波过程均导致SWNT含量随平均功率的增加而线性增加。这些结果对于脉冲激光的生产是不直观的,因为较高的平均功率对应于较低的峰值脉冲功率。实际上,最大脉冲能量为0.62 J / cm〜2(3 kHz,16W)的脉冲运行不会产生可检测的SWNT。最大SWNT内容为78

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