Catalytic Evaluation Of Al_2O_3-ZrO_2 Supports Used In The Reduction Of No With CH_4

摘要

The aim of this work is to prepare and characterize Al_2O_3-ZrO_2 powders by Pechine method and to evaluate them as supports for palladium catalysts in the selective reduction of NO with CH_4. The effect of aluminum ion on the final characteristics of the zirconia powder is also investigated. The catalytic supports were characterized by X-ray diffraction (XDR), scanning electron microscopy (SEM) and catalytic activity. The XRD data showed the formation of tetragonal zirconia phase, with crystallite size of 6.3 and 6.1 nm for the supports prepared with 0.1 and 0.5 moles of Al~(2+), respectively. Both supports showed porous and homogeneous agglomerates. Pd/Al_2O_3-ZrO_2 catalysts were active NO reduction by CH_4.