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EFFECT OF VISCOSITY MODIFYING AGENTS ON THE RHEOLOGY PROPERTIES OF CEMENT PASTE WITH POLYCARBOXYLATE SUPERPLATICIZER

机译:增粘剂对多羧酸盐超级增塑剂水泥浆流变性能的影响

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摘要

Viscosity modifying agents (VMA) can be used to enhance the viscosity of cement paste and avoid layered isolation of paste, so they are often associated with superplasticizer together to improve the stream state of mortar and concrete workability. Polycarboxylate superplasticizers (PC), which have high water reducing and flexible structures, are widely used in grouting materials and self-compacting concrete. However, the effect of different structures of polycarboxylate superplasticizers and viscosity modifying agents on rheological properties of cement paste is still lack of understand. In this paper, the relations of shear rate-shear stress and shear rate-apparent viscosity of cement paste with polycarboxylate superplaticizers and viscosity modifying agents were compared and the basic principle was put forward.The results showed that VMA had significant effect on rheological properties of cement paste. Apparent viscosity and yield value enhanced with the increasing of VMA dosage. The paste with VMA performed pseudoplasticity obviously. The effect of Xanthan Gum on the rbeological properties of the paste was larger than Welan Gum and hydroxyethyl ethers methyl cellulose (HEMC). At high shear rate, the influence of Welan Gum on paste added with ester PC was larger than with ethers PC.
机译:粘度调节剂(VMA)可用于提高水泥浆的粘度,避免浆状分层,因此它们通常与高效减水剂一起使用,以改善砂浆的流态和混凝土的可加工性。具有高减水率和柔性结构的聚羧酸类高效减水剂(PC)广泛用于灌浆材料和自密实混凝土中。然而,人们仍然不了解聚羧酸盐高效减水剂和粘度调节剂的不同结构对水泥浆流变性能的影响。本文比较了聚羧酸盐超级增塑剂和增粘剂对水泥浆的剪切速率-剪切应力和剪切速率-表观粘度的关系,并提出了基本原理。结果表明,VMA对水泥浆的流变性具有重要影响。水泥浆。随着VMA用量的增加,表观粘度和屈服值增加。 VMA糊剂具有明显的假塑性。黄原胶对糊剂的流变学特性的影响大于维兰胶和羟乙基醚甲基纤维素(HEMC)。在高剪切速率下,Welan Gum对添加酯PC的糊料的影响要大于醚PC。

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