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Application of electrochemical techniques for machining titanium aluminide-based alloys

机译:电化学技术在铝化钛基合金加工中的应用

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Intermetallic materials with excellent resistance to high temperature oxidation have been considered as potential replacements for superalloys used as aerospace materials. Titanium aluminides are especially attractive for this role (1-7). However, further commercialization of titanium aluminides requires the development of non-conventional machining, such as electrochemical machnining (ECM) (8). As a first attempt in the development of the ECM process, the corrosion behavior of arc-melted #gamma# TiAl and #alpha# 2 Ti_3Al was investigated along with pure titanium and aluminum in deaerated and non-deaerated solutions of sulfuric acid, sodium sulfate, and sodium hydroxide. Two types of electro-chemical experiments were carried out, namely: potentiodynamic and potentiostatic. In the Na_2SO_4 solution, the highest current was found for Al and the lowest for TiAl. The shape of the plarization curves indicates that the intermetallics show similar behavior to that of Ti.
机译:具有优异的耐高温氧化性的金属间材料已被认为是用作航空航天材料的高温合金的潜在替代品。铝化钛对于这种作用特别有吸引力(1-7)。然而,钛铝化物的进一步商业化需要开发非常规的机械加工,例如电化学机械加工(ECM)(8)。作为ECM工艺开发的首次尝试,研究了电弧熔化的#gamma#TiAl和#alpha#2 Ti_3Al以及纯钛和铝在硫酸,硫酸钠的脱气和非脱气溶液中的腐蚀行为。和氢氧化钠。进行了两种类型的电化学实验,即:电位动力学和恒电位。在Na_2SO_4溶液中,发现Al的电流最高,而TiAl的电流最低。极化曲线的形状表明金属间化合物的行为与Ti相似。

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