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Development of Electrochemical Method for Voltammetric Analysis of Tetradifon on Glassy Carbon Electrode

机译:电化学方法在玻璃碳电极上四氟苯磺酸伏安分析的方法开发

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摘要

The electrochemical determination of the pesticide Tetradifon (TDF) on glassy carbon electrode can be proposed as a faster and cheaper alternative compared to chromatographic methods commonly used in this analysis. The methodology was developed based on the measurement of electrical currents generated by redox processes of the analyte dispersed in a supporting electrolyte solution composed of a mixture of 40% dimethylformamide (DMF), 30% methanol, and 30% NaOH 0.3 mol L~(-1). Two electroanalytical techniques were employed: the cyclic voltammetry for qualitative studies of the redox processes of the compound and the differential pulse voltammetry that enabled the determination of TDF independently of the presence of a vegetable matrix, specifically Brazilian green bell pepper, culture in which the pesticide is widely used.
机译:与该分析中常用的色谱方法相比,可以建议在玻璃碳电极上电化学测定农药四氢噻嗪(TDF),作为一种更快,更便宜的替代方法。该方法是基于对分散在支持电解质溶液中的分析物的氧化还原过程产生的电流进行测量而开发的,该支持电解质溶液由40%二甲基甲酰胺(DMF),30%甲醇和30%NaOH 0.3 mol L〜(- 1)。使用了两种电分析技术:用于定性研究化合物氧化还原过程的循环伏安法和微分脉冲伏安法,其能够独立于蔬菜基质(特别是巴西青椒)的存在而测定TDF,在该培养物中使用农药被广泛使用。

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