Human factor, especially social factor in command and control organization, is an indispensable part of Cyber-physical-social System (CPSS) for Command and Control (C2). Based on the coordination theory, self-synchronization of a CPSS is both a self-organizing and self-adapting process, of which theend effect will be shown as the emergence of all the dependency relationshipsrnamong the COAs where the systems and human beings in CPSS would be in harmony. This article studi the command and control organization in the CPSS, proposed a CPSS modeling approach for CPSS in command and control domain. A CPSSfor command and control wbe modeled in different views：the system view, the human view and the coordination. This approach pays more attention to human factor and social network, which wimprove the vuhol a effectiveness i n a human-i n-loop system.
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