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Synthesis,crystal structure and magnetic property of a new layered copper(II) complex with picolinic acid N-oxide built from CU_2O_2 dimmer units

机译:CU_2O_2二聚体构成的新型吡啶甲酸N-氧化物层状铜(II)配合物的合成,晶体结构和磁性

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摘要

Reaction of copper(II) chloride with picolinic acid N-oxide (HL) in acetone/THF mixed solvent afforded a novel layered compound,[Cu(L)Cl(H_2O)]_2,in which each pair of octahedrally coordinated copper(II) ions are bridged by two N-oxide groups to form a CU_2O_2 dimeric unit,and such dimeric units are further interconnected via carboxylate groups to form a layer.
机译:氯化铜(II)与吡啶甲酸N-氧化物(HL)在丙酮/ THF混合溶剂中反应,得到一种新型的层状化合物[Cu(L)Cl(H_2O)] _ 2,其中每对八面体配位的铜(II)离子被两个N-氧化物基团桥接形成CU_2O_2二聚体单元,这些二聚体单元进一步通过羧酸酯基相互连接形成一层。

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