Cadmium complexes of meso-tetra-(p-chlorophenyl)porphyrin:[meso-tetra-(p-chlorophenyl)porphyrinato](pyridine)cadmium(II) pyridine solvate and [meso-tetra-(p-chlorophenyl)porphyrinato] (dimethylformamide)cadmium(II) toluene solvate

摘要

The crystal structures of [meso-tetra-(p-chlorophenyl)porphyrinato](pyridine)cadmium(II) pyridine solvate Cd[(p-Cl)4tpp](py) py [or 5 o py],and [meso-tetra-(p-chlorophenyl)porphyrinato](dimethylformamide)cadmium(II) toluene solvate Cd[(p-Cl)_4tpp](DMF) toluene [or 6 o toluene] were determined.The ring current effect provides a complementary method for the investigation of coordinated pyridine and DMF ligand in complexes 5 and 6,respectively.