A novel linear-chain material showing sandwiched stacking via alternative Pt(II)…Pt(II) or Pt(II)…S and pi…pi interactions

Biing-Chiau Tzeng; Gene-Hsiang Lee; Shie-Ming Peng

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A novel linear-chain material showing sandwiched stacking via alternative Pt(II)…Pt(II) or Pt(II)…S and pi…pi interactions

机译：一种新型的线性链材料，其通过交替的Pt（II）…Pt（II）或Pt（II）…S和pi…pi相互作用显示出夹心堆叠

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A novel linear-chain material,[Pt(8-QNS)_2][Pt(terpy)Cl]_2(ClO_4)_2 (8-QNS=8-quinolinethiolate;terpy=2,2':6',2"-terpyridine),has been serendipitously isolated and characterized by a crystallographic study.The title compound composed of alternative cationic [Pt(terpy)Cl]~+ pairs and [Pt(8-QNS)_2] moieties is formed by an interesting rearrangement process,and it shows sandwiched stacking via alternative Pt(II) or Pt(II)…Pt(II)…and pi…pi interactions.

机译：新型线性链材料[Pt（8-QNS）_2] [Pt（terpy）Cl] _2（ClO_4）_2（8-QNS = 8-quinolinethiolate; terpy = 2,2'：6'，2“-已通过晶体学研究意外地分离并鉴定了其特征。由有趣的重排过程形成了由交替的阳离子[Pt（terpy）Cl]〜+对和[Pt（8-QNS）_2]部分组成的标题化合物，它显示了通过替代的Pt（II）或Pt（II）…Pt（II）…和pi…pi相互作用进行的三明治式堆叠。

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《Inorganic Chemistry Communications》 |2003年第10期|共3页
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Biing-Chiau Tzeng; Gene-Hsiang Lee; Shie-Ming Peng;
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3. A novel linear-chain material showing sandwiched stacking via alternative Pt(II)…Pt(II) or Pt(II)…S and pi…pi interactions [J] . Biing-Chiau Tzeng, Gene-Hsiang Lee, Shie-Ming Peng Inorganic Chemistry Communications . 2003,第10期

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A novel linear-chain material showing sandwiched stacking via alternative Pt(II)…Pt(II) or Pt(II)…S and pi…pi interactions

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