Synthesis and Characterization of the First Mixed Alkali Metal Enoiate Containing Amine Ligands: A Nove! 'Open-Stack' Structure and !ts Implications for Aidol Addition

摘要

During the past two decades there has been an increasing awareness of the role that aggregation plays in the reactions of lithium enolales. This focus has been created by intercut in the aldol reaetion and in particular in the possibility of forming chiral mateiials from simple ketones [Eq.(a)].