Effect of the Metal-Assisted Assembling Mode on the Redox States of Hexaazatriphenylene Hexacarbonitrile

摘要

Metal-directed self-assembly through several molecular recognition events on polydentate ligands with a suitable arrangement of binding sites has provided a route for the spontaneous but controlled generation of supramolecular architectures.In particular,the properties of inorganic supramolecules with redox-active units are of intense interest with respect to their potential for application in sensors,machines,and electronic devices.